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https://open.uns.ac.rs/handle/123456789/9894| Title: | Some new ring-D seco steroids | Authors: | Miljković D. Petrović J. Hadžić P. |
Issue Date: | 1-Jan-1978 | Journal: | Tetrahedron | Abstract: | The Beckmann fragmentation product, 3-methoxy-17-oxo-16,17-secoestra-1,3,5(10)-trien-16-nitrile (2) has been reduced by LAH giving the expected 3-methoxy-17-hydroxy-16,17-secoestra-1,3,5(10-trien-16-amine hydrochloride (3) and 3-methoxy-17-oxa-D-homoestra-1,3,5(10)-trien-16-ol (4), by a presumed neighbouring group participation of 17-OH group in the intermediary formed 16-imino derivative (A). The structure of 4 has been proved by an alternative synthetic route by reducing 3-methoxy-17-oxa-D-homoestra-1,3,5(10)-trien-16-one (7) with di-iso-butylaluminium hydride. © 1978. | URI: | https://open.uns.ac.rs/handle/123456789/9894 | ISSN: | 00404020 | DOI: | 10.1016/0040-4020(78)88434-8 |
| Appears in Collections: | Naučne i umetničke publikacije |
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