Please use this identifier to cite or link to this item: https://open.uns.ac.rs/handle/123456789/9894
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dc.contributor.authorMiljković D.en
dc.contributor.authorPetrović J.en
dc.contributor.authorHadžić P.en
dc.date.accessioned2020-03-03T14:35:45Z-
dc.date.available2020-03-03T14:35:45Z-
dc.date.issued1978-01-01en
dc.identifier.issn00404020en
dc.identifier.urihttps://open.uns.ac.rs/handle/123456789/9894-
dc.description.abstractThe Beckmann fragmentation product, 3-methoxy-17-oxo-16,17-secoestra-1,3,5(10)-trien-16-nitrile (2) has been reduced by LAH giving the expected 3-methoxy-17-hydroxy-16,17-secoestra-1,3,5(10-trien-16-amine hydrochloride (3) and 3-methoxy-17-oxa-D-homoestra-1,3,5(10)-trien-16-ol (4), by a presumed neighbouring group participation of 17-OH group in the intermediary formed 16-imino derivative (A). The structure of 4 has been proved by an alternative synthetic route by reducing 3-methoxy-17-oxa-D-homoestra-1,3,5(10)-trien-16-one (7) with di-iso-butylaluminium hydride. © 1978.en
dc.relation.ispartofTetrahedronen
dc.titleSome new ring-D seco steroidsen
dc.typeJournal/Magazine Articleen
dc.identifier.doi10.1016/0040-4020(78)88434-8en
dc.identifier.scopus2-s2.0-0018216932en
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/0018216932en
dc.relation.lastpage3577en
dc.relation.firstpage3575en
dc.relation.issue24en
dc.relation.volume34en
item.grantfulltextnone-
item.fulltextNo Fulltext-
Appears in Collections:Naučne i umetničke publikacije
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