Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/20311
Title: | Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand | Authors: | Perić Marko Kyne Sara H. Gruden Maja Rodić Marko Jeremić Dejan Stanković Dalibor M. Brčeski Ilija |
Issue Date: | 2019 | Journal: | Monatshefte fur Chemie | Abstract: | © 2019, Springer-Verlag GmbH Austria, part of Springer Nature. Abstract: In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic. | URI: | https://open.uns.ac.rs/handle/123456789/20311 | ISSN: | 0026-9247 1434-4475 |
DOI: | 10.1007/s00706-019-02405-7 |
Appears in Collections: | PMF Publikacije/Publications |
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