Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand

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Назив:	Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
Аутори:	Perić Marko Kyne Sara H. Gruden Maja Rodić Marko Jeremić Dejan Stanković Dalibor M. Brčeski Ilija
Датум издавања:	2019
Часопис:	Monatshefte fur Chemie
Сажетак:	© 2019, Springer-Verlag GmbH Austria, part of Springer Nature. Abstract: In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
URI:	https://open.uns.ac.rs/handle/123456789/20311
ISSN:	0026-9247 1434-4475
DOI:	10.1007/s00706-019-02405-7
Налази се у колекцијама:	PMF Publikacije/Publications