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https://open.uns.ac.rs/handle/123456789/20311
Nаziv: | Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand | Аutоri: | Perić Marko Kyne Sara H. Gruden Maja Rodić Marko Jeremić Dejan Stanković Dalibor M. Brčeski Ilija |
Dаtum izdаvаnjа: | 2019 | Čаsоpis: | Monatshefte fur Chemie | Sažetak: | © 2019, Springer-Verlag GmbH Austria, part of Springer Nature. Abstract: In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic. | URI: | https://open.uns.ac.rs/handle/123456789/20311 | ISSN: | 0026-9247 1434-4475 |
DOI: | 10.1007/s00706-019-02405-7 |
Nаlаzi sе u kоlеkciјаmа: | PMF Publikacije/Publications |
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