Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1 ^-)] nickel(II)

Abstract

The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Å from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. © 2003 Published by Elsevier B.V.