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https://open.uns.ac.rs/handle/123456789/31746
Title: | Synthesis, structure and photoluminescence of (PLAGH)2[ZnCl4] and comparative analysis of photoluminescence properties with tris(2,2‚-bipyridine)-ruthenium(II) | Authors: | Radanović, Mirjana Jelić, Miodrag Romčević, Nebojša Boukos, Nikos Vojinović-Ješić, Ljiljana Leovac, Vukadin Hadžić, Branka Bajac, Branimir Nađ, Laslo Chrysoula, Chandrinou Baloš, Sebastian |
Issue Date: | 2015 | Journal: | Materials Research Bulletin | Abstract: | The first compound of zinc(II) containing pyridoxalaminoguanidine has been synthesized and characterized by elemental analysis, infrared spectra, conductometric measurements and X-ray crystallography. Single crystals of the compound were obtained in the reaction of methanolic solution of zinc(II) chloride and pyridoxalaminoguanidine hydrochloride. In this compound the coordination of chelate ligand is absent and tetrachlorido complex of zinc(II) with pyridoxalaminuguanidinium cation as contraion is obtained. Photoluminescence spectra were measured. Lorentzian multipeak technique was used to determine peak wavelengths and their intensities. Photoluminescence spectroscopy upon 325, 488 and 514 nm laser excitation light was used to obtain results. This novel compound of zinc(II) was compared to the well-known organic light emitting diode material—ruthenium(II) complex with bypiridine i.e., tris(2,2′-bipyridine)ruthenium(II), under the same circumstances and the identical experimental setup. A scheme of energy levels and transitions is proposed to explain the obtained experimental results. | URI: | https://open.uns.ac.rs/handle/123456789/31746 | ISSN: | 0025-5408 | DOI: | 10.1016/j.materresbull.2015.06.034 |
Appears in Collections: | FTN Publikacije/Publications |
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