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https://open.uns.ac.rs/handle/123456789/31319
Title: | Conversion of D-xylose to protected D-lyxose derivatives and to D-lyxose, via the corresponding 1,2-anhydride | Authors: | Popsavin Velimir Grabež S Stojanović Bojana Popsavin Mirjana Pejanović V. Miljković D. |
Issue Date: | 1999 | Journal: | Carbohydrate Research | Abstract: | Acid hydrolysis of 3,5-di-O-benzyl-1,2-O-cyclohexylidene-α-D-xylofuranose gave the corresponding lactol, which was subsequently converted to the 3,5-di-O-benzyl-2-O-mesyl-D-xylofuranose. This compound readily reacted with sodium methoxide, sodium benzylate or sodium hydroxide (presumably via the corresponding 1,2-anhydride) to give the protected D-lyxofuranosides. These compounds were finally converted to methyl α-D-lyxopyranoside or to D-lyxose. Copyright (C) 1999 Elsevier Science Ltd. | URI: | https://open.uns.ac.rs/handle/123456789/31319 | ISSN: | 0008-6215 | DOI: | 10.1016/S0008-6215(99)00164-0 |
Appears in Collections: | PMF Publikacije/Publications |
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