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https://open.uns.ac.rs/handle/123456789/28689
Nаziv: | Synthesis, structure and biological activities of Pd(II) and Pt(II) complexes with 2-(diphenylphosphino)benzaldehyde 1-adamantoylhydrazone | Аutоri: | Đorđević Milena Jeremić Dejan Rodić Marko Simić Vera Brčeski I.D. Leovac Vukadin |
Dаtum izdаvаnjа: | 2014 | Čаsоpis: | Polyhedron | Sažetak: | The reaction of an ethanolic solution of the newly synthesized 2-(diphenylphosphino)benzaldehyde 1-adamantoylhydrazone (HL) with aqueous solutions of K2[MCl4] (M = Pd(II), Pt(II)) resulted in neutral complexes of the general formulae [M(L)Cl]. These complexes have a square-planar structure that was achieved by tridentate PNO coordination of the monoprotonated Schiff base and a chloride ligand. The ligand and its metal complexes were analyzed for their antimicrobial activity and their in vitro cytotoxicity in human larynx carcinoma cells (Hep-2) and non-cancerous human lung fibroblast cells (MRC-5). The platinum(II) complex shows cytotoxicity towards Hep-2 cells comparable to oxaliplatin and exhibited improved selectivity for cancer cells. The ligand and its complexes were characterized by elemental analysis, NMR and IR spectroscopy, and single crystal X-ray diffraction analysis. © 2013 Elsevier Ltd. All rights reserved. | URI: | https://open.uns.ac.rs/handle/123456789/28689 | ISSN: | 0277-5387 | DOI: | 10.1016/j.poly.2013.10.029 |
Nаlаzi sе u kоlеkciјаmа: | PMF Publikacije/Publications |
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