Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/19910
Title: | Ultraviolet/Hydrogen Peroxide Oxidative Degradation of 1,2,3-Trichlorobenzene: Influence of Water Matrix and Toxicity Assessment | Authors: | Đurkić Tajana Molnar Jazić Jelena Kragulj Isakovski Marijana Maletić Snežana Tubić Aleksandra Dalmacija Božo Agbaba Jasmina |
Issue Date: | 2019 | Journal: | Environmental Engineering Science | Abstract: | © Copyright 2019, Mary Ann Liebert, Inc., publishers 2019. This article investigates the effects of different water matrices emphasizing the influence of humic matter and alkalinity on the performance of ultraviolet/hydrogen peroxide (UV/H2O2) process for the degradation of 1,2,3-trichlorobenzene (TCB) in water. Due to the threat it poses to the aquatic environment and human health, TCB has been identified as a priority pollutant by the European Water Framework Directive. Under direct UV photolysis a very similar degree of TCB degradation (up to 48% depending on applied UV fluence) was achieved in synthetic matrices containing humic acids (HA) and hydrogencarbonate (HCO3-) and in natural waters. UV/H2O2 process significantly improves TCB degradation, where synthetic matrix containing HA and natural waters require application of higher H2O2 concentration to achieve >90% of TCB degradation. TCB degradation kinetics indicate that the highest inhibiting effect was observed for the matrix with a high HA concentration (12 mg C/L) and in groundwater rich in natural organic matter (NOM). TCB degradation occurred through 2,3,4-trichlorophenol as an oxidation intermediate leading to the formation of C2-C4 carboxylic acids as final products. A reduction in NOM aromaticity and aldehyde formation was observed in the treated natural waters. The bioassay with Vibrio fischeri shows that a slight inhibition of bioluminescence recorded for untreated samples was not significantly changed during UV photolysis or by the UV/H2O2 process with 1 mg H2O2/L (10-18% of inhibition), but applying higher H2O2 concentrations rapidly increased the inhibition indicating the formation of more toxic intermediates of TCB and NOM during oxidation. | URI: | https://open.uns.ac.rs/handle/123456789/19910 | ISSN: | 1092-8758 | DOI: | 10.1089/ees.2019.0020 |
Appears in Collections: | PMF Publikacije/Publications |
Show full item record
SCOPUSTM
Citations
5
checked on May 10, 2024
Page view(s)
24
Last Week
7
7
Last month
6
6
checked on May 10, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.