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https://open.uns.ac.rs/handle/123456789/17488
Title: | Crystal structure of K[PtCl <inf>3</inf> (caffeine)] and its interactions with important nitrogen-donor ligands | Authors: | Snežana Jovanović Ralph Puchta Klisurić Olivera Zivadin Bugarcic |
Issue Date: | 2016 | Journal: | Journal of Coordination Chemistry | Abstract: | © 2016 Taylor & Francis. The crystal structure of K[PtCl 3 (caffeine)] was determined. The coordination geometry around platinum is square-planar formed by N9 of the caffeine ligand and three Cl - ions. The bond lengths and angles of K[PtCl 3 (caffeine)] were compared with those reported for [PtCl 3 (caffeine)] - and K[PtCl 3 (theobromine)]. At the level of the statistical significance of the data we have compared, no differences in the bond distances and angles for any of these compounds were noticed. Weak interactions between K + and Cl - are responsible for the formation of 1-D polymeric chains in the crystal structure of the complex. The interactions of K[PtCl 3 (caffeine)] with inosine (Ino) and guanosine-5′-monophosphate (5′-GMP) were studied by 1 H NMR spectroscopy at 295 K in D 2 O in a molar ratio of 1: 1. The results indicate formation of the reaction product [PtCl 3 (Nu)] (Nu=Ino or 5′-GMP) with the release of caffeine from the coordination sphere of the starting complex. The higher stability of the bond between the Pt(II) ion and Ino or 5′-GMP compared to the stability of the platinum-caffeine bond is confirmed by density functional theory calculations (B3LYP/LANL2DZp) using as models 9-methylhypoxanthine and 9-methylguanine. | URI: | https://open.uns.ac.rs/handle/123456789/17488 | ISSN: | 0095-8972 1029-0389 |
DOI: | 10.1080/00958972.2016.1146257 |
Appears in Collections: | PMF Publikacije/Publications |
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