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https://open.uns.ac.rs/handle/123456789/16222
Title: | Electrochemical polymerization of 2-methyl-1-naphthylamine | Authors: | Ciric-Marjanovic G. Cvjetićanin N. Mentus S. Budinski-Simendić, Jaroslava Krakovsky I. |
Issue Date: | 1-Jan-2003 | Journal: | Polymer Bulletin | Abstract: | 2-methyl-1-naphthylamine has been electropolymerized from the acidic aqueous solutions by three different synthetic routes. The polymerization products, deposited at a platinum working electrode as very adherent films, were characterized by cyclic voltammetry (CV), infrared spectroscopy (IR) and gel permeation chromatography (GPC). In a strongly acidic medium, the products display redox properties, in a form of two well-defined redox pairs with the formal potentials at 0.19 V and 0.47 V vs. SCE. IR-spectroscopy indicated that the polymerization occurs via the -NH2 groups, by different coupling ways: N-C(4), N-C(5) and N-C(7), as well as that ClO4- ions incorporate themselves into the product of electropolymerization. GPC of the polymerization products evidenced oligomeric chains with molar masses up to 1600 g/mol as main species. | URI: | https://open.uns.ac.rs/handle/123456789/16222 | ISSN: | 01700839 | DOI: | 10.1007/s00289-003-0174-8 |
Appears in Collections: | TF Publikacije/Publications |
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