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https://open.uns.ac.rs/handle/123456789/15763
Title: | Synthesis and characterisation of a novel polymeric Cd complex, catena-(μ-thio)[bisN-phenylthiourea] bis(dimethylsulphoxide) dichlorocadmium(II) | Authors: | Mesaroš-Sečenji (Mészáros Szécsényi), Katalin Leovac V. Evans I. |
Issue Date: | 20-Mar-2006 | Journal: | Journal of Coordination Chemistry | Abstract: | A new Cd(II) complex, [CdL(DMSO)2Cl2]n, L = bis(N-phenylthiourea), has been synthesized and its crystal structure determined from single-crystal diffraction data. The compound is orthorhombic, space group Pna21, with a = 18.728(1), b = 12.2601(8), c = 22.879(1) Å, V = 5253.3(6) Å3. L acts as an exobidentate neutral ligand and Cd is octahedral, being bonded to two S atoms, two terminal Cl ions and two DMSO solvent molecules. The structure is that of a one-dimensional polymer, with chains running parallel to the b axis. Polymeric chains are stabilized by N-H⋯Cl hydrogen bonding, while intermolecular S⋯O contacts connect the chains. Thermal decomposition of the complex starts at 120°C by desolvation and is continuous over the recorded temperature range. © 2006 Taylor & Francis. | URI: | https://open.uns.ac.rs/handle/123456789/15763 | ISSN: | 00958972 | DOI: | 10.1080/00958970500171240 |
Appears in Collections: | PMF Publikacije/Publications |
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