Молимо вас користите овај идентификатор за цитирање или овај линк до ове ставке:
https://open.uns.ac.rs/handle/123456789/15429
Назив: | Strong metal-support interaction as activity requirement of palladium-supported tin oxide sol-gel catalyst for water denitration | Аутори: | Bošković, Goran Kovačević, M. Kiss, Ernő Radnik, J. Pohl, M. Schneider, M. Bentrup, U. Bruckner, A. |
Датум издавања: | 1-апр-2012 | Часопис: | International Journal of Environmental Science and Technology | Сажетак: | Two nanocrystalline palladium-supported tin oxide catalysts for water denitration were synthesized by a modified sol-gel technique using appropriate chloride precursors for both support and active phases, and citric acid to tune the rate of hydrolysis and condensation. The difference among sample preparation procedures refers to the moment of the noble metal loading to the support, as well as to the calcination temperature altitude followed. Thus, mesoporous tin oxide was synthesized by a sol-gel method following calcination at 700°C. The palladium active phase was introduced afterwards by means of palladium chloride solution impregnation, followed by calcination at 400°C (sample 1). Alternatively, simultaneous complexation of both metal and support precursors followed by single calcination at 700°C was applied for preparation of sample 2. The former sample showed higher activity and selectivity in hydro-denitration of water model system initially containing 100 ppm of nitrates. This was explained by preferential textural, morphological and structural properties accomplished by early contact of metal and support nanoparticles, while achieved by calcination at high single temperature forcing diffusion of palladium ions into the tin oxide matrix. The outcome is very well distribution of palladium and strong metal-support interaction leading to multivalent tin. This indicates partly reduced tin oxide formation in the course of its reduction in hydrogen, which may act as active site in denitration reaction. © 2012 CEERS, IAU. | URI: | https://open.uns.ac.rs/handle/123456789/15429 | ISSN: | 17351472 | DOI: | 10.1007/s13762-012-0029-7 |
Налази се у колекцијама: | TF Publikacije/Publications |
Приказати целокупан запис ставки
SCOPUSTM
Навођења
3
проверено 03.05.2024.
Преглед/и станица
14
Протекла недеља
8
8
Протекли месец
0
0
проверено 10.05.2024.
Google ScholarTM
Проверите
Алт метрика
Ставке на DSpace-у су заштићене ауторским правима, са свим правима задржаним, осим ако није другачије назначено.