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https://open.uns.ac.rs/handle/123456789/14886| Title: | A novel rearrrangement of steroidal α-hydroxy grimes | Authors: | Miljković, Dušan Penov-Gaši, Katarina Đurendić, Evgenija Sakač, Marija Medić-Mijačević, Ljubica Pejanović, Vjera Stanković, Slobodanka Lazar, Dušan |
Issue Date: | 30-Jun-1997 | Journal: | Tetrahedron Letters | Abstract: | By the action of acidic titanium trichloride upon 16-oximino-17α-benzyl-17α-hydroxy derivatives in the androstane and estrane series the 16-oxo-17-β-benzyl-17α-hydroxy derivatives 6 and 7 with inversed configuration at C17 were obtained. A mechanism for this novel rearrangement is proposed. | URI: | https://open.uns.ac.rs/handle/123456789/14886 | ISSN: | 00404039 | DOI: | 10.1016/S0040-4039(97)00996-9 |
| Appears in Collections: | PMF Publikacije/Publications |
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