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https://open.uns.ac.rs/handle/123456789/14832
Title: | Voltammetric and titrimetric study of acid-base properties of some μ-oxo dimeric iron(III) complexes in DMF | Authors: | Jovanović L. Ević N. Bjelica L. Abramović, Biljana Gaál F. Rehák N. |
Issue Date: | 1-Jan-1992 | Journal: | Monatshefte für Chemie Chemical Monthly | Abstract: | The acid-base properties of the μ-oxo bridged dimeric iron complexes [Fe L]2O with the ligands based on S-alkyl-1,4-bis(substituted salicylidene)isothiosemicarbazide and a tetramer with S-methyl-1,4-bis(salicylidene)isothiosemicarbazide, {[Fe L]2O}2I3·I2, were investigated by cyclic voltammetry at glassy carbon electrode in DMF. Studies were carried out in the presence of either a weak (phenol) or a strong (HClO4 aq.) acid. The stoichimoetry of the reaction, changes in the general voltammetric pattern and the electrode reaction mechanism were discussed. These studies served as the basis for three-electrode amperometric titrations to determine the content of several of these complexes. © 1992 Springer-Verlag. | URI: | https://open.uns.ac.rs/handle/123456789/14832 | ISSN: | 00269247 | DOI: | 10.1007/BF00808269 |
Appears in Collections: | PMF Publikacije/Publications |
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