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Title: | Pyridine-type complexes of transition-metal halides XIII: Solid state studies of copper(II) chloride and bromide complexes with methylpyridines - Part II: Complexes with 2- and 4-methylpyridine and 2,4,6-collidine | Authors: | Mesaroš-Sečenji (Mészáros Szécsényi), Katalin Wadsten T. Carson B. Bencze E. Kenessey G. Liptay G. |
Issue Date: | 14-Dec-1999 | Journal: | Thermochimica Acta | Abstract: | This study is concerned with the reactions between copper(II) chloride and bromide with 2- and 4-methylpyridine and 2,4,6-collidine. The effects of the methyl groups(s)' position in a series of methylpyridines on the host-guest phenomenon in the formed copper(II) halide compounds were studied using thermogravimetry, far-infrared and electronic spectroscopy and X-ray diffraction. Copper(II) halide complexes with 4-methylpyridine and the copper(II) chlorido complex with 2,4,6-collidine exhibit zeolite properties. The reaction of copper(II) halides with 2-methylpyridine resulted in complex formation but no host-guest phenomenon was detected in these complexes. No complex formation was observed between 2,4,6-collidine and copper(II) bromide. © 1999 Elsevier Science B.V. | URI: | https://open.uns.ac.rs/handle/123456789/13338 | ISSN: | 00406031 |
Appears in Collections: | PMF Publikacije/Publications |
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