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https://open.uns.ac.rs/handle/123456789/13323
Title: | Transition metal complexes with pyrazole-derived ligands. XI. [Zn(μ-L)(HL)(OAc)]2 (HL is 4-acetyl-3-amino-5-methylpyrazole) | Authors: | Tomić Z. Jaćimović Z. Leovac, Vukadin Ćešljević, Valerija |
Issue Date: | 1-Jan-2000 | Journal: | Acta Crystallographica, Section C: Crystal Structure Communications | Abstract: | The title compound, bis(μ-4-acetyl-3-amino-5-methylpyrazolato-N1:N2) bis[(acetato-O)(4-acetyl-3-amino-5-methylpyrazole-N2) zinc(II)], [Zn2(C6H8N3O)2 (C2H3O2)2(C6H9N3O)2], exists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination. | URI: | https://open.uns.ac.rs/handle/123456789/13323 | ISSN: | 01082701 | DOI: | 10.1107/S0108270100004881 |
Appears in Collections: | Naučne i umetničke publikacije |
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