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https://open.uns.ac.rs/handle/123456789/11421
Title: | Cobalt(II) complexes with aminopolycarboxylate 1,3-pdta-type ligands: Synthesis and characterization of trans(O <inf>6</inf> )-[Mg(H <inf>2</inf> O) <inf>6</inf> ][Co <sup>II</sup> (1,3-pddadp)]•H <inf>2</inf> O | Authors: | Draškovi N. Djuran M. Cvijović M. Radanović D. D. Jevtović V. |
Issue Date: | 1-Jan-2004 | Journal: | Transition Metal Chemistry | Abstract: | Starting from Ba 2 (1,3-pddadp)•8H 2 O (1,3-pddadp=1,3-propanediamine-N,N′-diacetate-N,N′-di-3-propionate ion) and CoSO 4 , a new hexadentate [Co II (1,3-pddadp)] 2- complex has been prepared. The trans(O 6 ) geometry of this complex was confirmed by comparison of its i.r. and u.v.-vis. spectra with those of [Co II (1,3-pdta)] 2- (1,3-pdta is the 1,3-propanediaminetetraacetate ion) and trans(O 6 )-[Co III (1,3-pddadp)] - complexes of known X-ray crystal structure. Magnetic and electrolytic conductivity properties of these complexes have also been discussed. © 2004 Kluwer Academic Publishers. | URI: | https://open.uns.ac.rs/handle/123456789/11421 | ISSN: | 3404285 | DOI: | 10.1007/s11243-004-2239-4 |
Appears in Collections: | PMF Publikacije/Publications |
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