Large single crystals of isomorphous hexaaquametal(II) D-camphor10- sulfonates

Abstract

Novel hexaaquametal(II) bis(D-camphor-10-sulfonates) with Mn(II), Fe(II), and Co(II) ions were synthesized as large single crystals. During the crystallization process, suitable metal wires were used to induce crystallization. Crystals were analyzed by means of X-ray analysis, IR spectrophotometry, and solid state UV-vis spectroscopy. The obtained substances are stable in air, and their UV-vis spectra imply their potential use as optical filters and optical materials. © 2009 American Chemical Society.