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https://open.uns.ac.rs/handle/123456789/10101
Title: | Biamperometric neutralisation titrations in non-aqueous solvents applying tin electrode pair for the end-point detection | Authors: | Gaál F. Leovac V. Avramović B. |
Issue Date: | 1-Jan-1973 | Journal: | Fresenius' Zeitschrift für Analytische Chemie | Abstract: | Tertiary amines and salts of organic acids in acetic anhydride with 5% of acetic acid were titrated applying a biamperometric indicating system consisting of a polarised or unpolarised pair of tin electrodes by means of 0.1 N perchloric acid in glacial acetic acid. Amounts of 15.4-29.8 mg were analysed with average deviations of <0.6%, the results obtained being in a good agreement with those of potentiometry. The biamperometric end-point detection using an indicating system of polarised pair of tin electrodes can be applied for coulometric determinations of these bases with satisfying accuracy. By means of anodic generation of hydrogen ions in the presence of hydroquinone amounts of 0.5-1.0 mg were titrated with average deviations of < 1.3%. The results obtained were compared with those obtained of catalytic thermometric and photometric titrations. © 1973 Springer-Verlag. | URI: | https://open.uns.ac.rs/handle/123456789/10101 | ISSN: | 00161152 | DOI: | 10.1007/BF00423764 |
Appears in Collections: | PMF Publikacije/Publications |
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