Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/8785
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Marković, Svetlana | en_US |
dc.contributor.author | Marković, Violeta | en_US |
dc.contributor.author | Joksović, Milan | en_US |
dc.contributor.author | Todorović, Nina | en_US |
dc.contributor.author | Joksović, Ljubinka | en_US |
dc.contributor.author | Divjaković, Vladimir | en_US |
dc.contributor.author | Trifunović, Snežana | en_US |
dc.date.accessioned | 2019-09-30T09:11:11Z | - |
dc.date.available | 2019-09-30T09:11:11Z | - |
dc.date.issued | 2013-07-31 | - |
dc.identifier.issn | 01035053 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/8785 | - |
dc.description.abstract | Reductive debromination of endo-(+)-3-bromocamphor with different primary amines followed by imine formation was investigated. This reaction requires simple experimental procedure without any organic solvent, metal or conventional reducing agent. A strong influence of amine polarity on the efficacy of debromination process was observed, and ethanolamine and ethylene diamine having sufficiently high boiling points can debrominate 3-bromocamphor giving corresponding camphanimines in good isolated yields. The mechanisms of debromination of 3-bromocamphor with ethanolamine and n-hexylamine were investigated at the B3LYP/6-311+G(d,p) level of theory. The radical mechanism was revealed, and it was shown that the reaction with more polar ethanolamine is energetically more favorable. © 2013 Sociedade Brasileira de Química. | en |
dc.relation.ispartof | Journal of the Brazilian Chemical Society | en |
dc.title | Debromination of endo-(+)-3-bromocamphor with primary amines | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.doi | 10.5935/0103-5053.20130144 | - |
dc.identifier.scopus | 2-s2.0-84880656725 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84880656725 | - |
dc.description.version | Unknown | en_US |
dc.relation.lastpage | 1108 | en |
dc.relation.firstpage | 1099 | en |
dc.relation.issue | 7 | en |
dc.relation.volume | 24 | en |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
Appears in Collections: | Naučne i umetničke publikacije |
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