Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/7847
DC Field | Value | Language |
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dc.contributor.author | Mirković, Milan | en |
dc.contributor.author | Nikolić, Nebojša | en |
dc.contributor.author | Mijin D. | en |
dc.contributor.author | Ivić, Maja | en |
dc.contributor.author | Kapor A. | en |
dc.contributor.author | Tomić, Zdenko | en |
dc.date.accessioned | 2019-09-30T09:04:49Z | - |
dc.date.available | 2019-09-30T09:04:49Z | - |
dc.date.issued | 2014-01-01 | en |
dc.identifier.issn | 03525139 | en |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/7847 | - |
dc.description.abstract | The diimine-dioxime ligand, 3,3'-(1,4-butanediyl-dinitrilo)bis-2- -pentanone, 2,2'-dioxime (LH2), containing a N4 donor set was prepared by the Schiff base condensation of 2-hydroxyimino-3-pentanone and 1,4-diaminobutane in two ways: in a protic and in an aprotic solvent. A higher yield of the (LH2) imine was obtained when the synthesis was performed using a protic solvent (C2H5OH) instead of aprotic benzene (78 and 30 %, respectively). The Cu(II) metal complex of diimine-dioxime was synthesized in CH3OH from the perchlorate salt of LH2 in a 1:1 mole ratio. The isolated complex was characterized by the elemental analysis, IR spectroscopy and cyclic voltammetry. The structure of [Cu2(LH)2](ClO4)2 was determined by single-crystal X-ray diffraction analysis. Comparison with structurally related diimine-dioxime Cu(II) complexes revealed the influence of a weak Cu...O(perchlorate) interaction on the geometry of the metallocycle. © 2014 SCS. All rights reserved. | en |
dc.relation.ispartof | Journal of the Serbian Chemical Society | en |
dc.title | Synthesis, characterization and crystal structure of Cu(II) complex with a diimine-dioxime ligand, [Cu2(LH)2](ClO4)2. Influence of the weak Cu...O(perchlorate) interaction on the structure of the Cu2N2O2 metallocycle | en |
dc.type | Journal/Magazine Article | en |
dc.identifier.doi | 10.2298/JSC130910120M | en |
dc.identifier.scopus | 2-s2.0-84901443748 | en |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84901443748 | en |
dc.relation.lastpage | 556 | en |
dc.relation.firstpage | 545 | en |
dc.relation.issue | 5 | en |
dc.relation.volume | 79 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
crisitem.author.orcid | https://orcid.org/0000-0001-7737-5992 | - |
Appears in Collections: | TF Publikacije/Publications |
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