Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/28686
DC Field | Value | Language |
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dc.contributor.author | Poleti Dejan | - |
dc.contributor.author | Rogan J. | - |
dc.contributor.author | Radovanović Lidija | - |
dc.contributor.author | Rodić Marko | - |
dc.date.accessioned | 2020-12-14T15:42:58Z | - |
dc.date.available | 2020-12-14T15:42:58Z | - |
dc.date.issued | 2014 | - |
dc.identifier.issn | 0352-5139 | - |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/28686 | - |
dc.description.abstract | The title compound, (Hdipya)(H3pyr), where Hdipya is protonated 2,2'-dipyridilamine and H3pyr is the monoanion of pyromellitic acid (H4pyr), was obtained from a reaction mixture containing Zn(II) ions, dipya, Na4pyr (in the mole ratio 2:2:1) and HNO3. The products (micro- and single-crystalline) were characterized by X-ray structure determination, FT-IR spectroscopy and TG/DSC analysis. The most striking structural feature of (Hdipya)(H3pyr) are short inter- and extremely short intramolecular hydrogen bonds. These bonds mutually connect cations and anions making thin layers parallel to the crystallographic (223) plane. In addition, quite unusual, linear proton-bound polymeric {H(H2pyr) -}n were identified in the structure. The results of crystal structure determination are compared with FT-IR and TG/DSC data. The low position of the νas(COO) vibration at 1660 cm-1 is in accordance with strong hydrogen bonding. This value could be used as a measure of the C=O bond order, which was calculated to be 1.81. © 2014 SCS. All rights reserved. | - |
dc.language.iso | en | - |
dc.relation.ispartof | Journal of the Serbian Chemical Society | - |
dc.source | CRIS UNS | - |
dc.source.uri | http://cris.uns.ac.rs | - |
dc.title | Structural, spectral and thermal properties of 2-(2-pyridylamino)pyridinium trihydrogen pyromellitate | - |
dc.type | Journal/Magazine Article | - |
dc.identifier.doi | 10.2298/JSC130706115P | - |
dc.identifier.scopus | 2-s2.0-84903129234 | - |
dc.identifier.url | https://www.cris.uns.ac.rs/record.jsf?recordId=84613&source=BEOPEN&language=en | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84903129234 | - |
dc.relation.lastpage | 648 | - |
dc.relation.firstpage | 637 | - |
dc.relation.issue | 6 | - |
dc.relation.volume | 79 | - |
dc.identifier.externalcrisreference | (BISIS)84613 | - |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
crisitem.author.dept | Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.orcid | 0000-0002-4471-8001 | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
Appears in Collections: | PMF Publikacije/Publications |
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