Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/28430
DC Field | Value | Language |
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dc.contributor.author | Novaković B. Slađana | - |
dc.contributor.author | Bogdanović A. | - |
dc.contributor.author | Leovac Vukadin | - |
dc.contributor.author | Rodić Marko | - |
dc.contributor.author | Vojinović-Ješić Ljiljana | - |
dc.contributor.author | Ivković Sonja | - |
dc.date.accessioned | 2020-12-14T15:20:19Z | - |
dc.date.available | 2020-12-14T15:20:19Z | - |
dc.date.issued | 2013 | - |
dc.identifier.issn | 0108-2701 | - |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/28430 | - |
dc.description.abstract | The title compound, C9H13N4O3+·NO3-, is the first structurally characterized Schiff base derived from semicarbazide and pyridoxal. Unusually for an unsubstituted semicarbazone, the compound adopts a syn conformation, in which the carbonyl O atom is in a cis disposition relative to the azomethine N atom. This arrangement is supported by a pair of hydrogen bonds between the organic cation and the nitrate anion. The cation is essentially planar, with only a hydroxymethyl O atom deviating significantly from the mean plane of the remaining atoms (r.m.s. deviation of the remaining non-H atoms = 0.01 Å). The molecules are linked into flat layers by N - H⋯O and C - H⋯O hydrogen bonds. O - H⋯O hydrogen bonds involving the hydroxymethyl group as a donor interconnect the layers into a three-dimensional structure. © 2013 International Union of Crystallography. | - |
dc.language.iso | en | - |
dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | - |
dc.source | CRIS UNS | - |
dc.source.uri | http://cris.uns.ac.rs | - |
dc.title | (E)-4-[(2-Carbamoylhydrazinylidene)methyl]-3-hydroxy-5-hydroxymethyl-2- methylpyridin-1-ium nitrate | - |
dc.type | Journal/Magazine Article | - |
dc.identifier.doi | 10.1107/S0108270113013929 | - |
dc.identifier.pmid | 69 | - |
dc.identifier.scopus | 2-s2.0-84880179167 | - |
dc.identifier.url | https://www.cris.uns.ac.rs/record.jsf?recordId=83859&source=BEOPEN&language=en | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84880179167 | - |
dc.relation.lastpage | 764 | - |
dc.relation.firstpage | 761 | - |
dc.relation.issue | 7 | - |
dc.relation.volume | 69 | - |
dc.identifier.externalcrisreference | (BISIS)83859 | - |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
crisitem.author.dept | Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.dept | Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.orcid | 0000-0002-4471-8001 | - |
crisitem.author.orcid | 0000-0002-8618-7819 | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
Appears in Collections: | PMF Publikacije/Publications |
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