Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/16274
DC Field | Value | Language |
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dc.contributor.author | Leovac, Vukadin | en_US |
dc.contributor.author | Divjaković, Vladimir | en_US |
dc.contributor.author | Fazlić R. | en_US |
dc.contributor.author | Engel P. | en_US |
dc.date.accessioned | 2020-03-03T15:03:16Z | - |
dc.date.available | 2020-03-03T15:03:16Z | - |
dc.date.issued | 1989-04-01 | - |
dc.identifier.issn | 03404285 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/16274 | - |
dc.description.abstract | The reaction of a warm ethanolic solution of CoII perchlorate or rodanide and NiII acetate with 2-furaldehyde S-methylisothiosemicarbazone (HL), yielded the complexes [Co(HL)2(H2O)](ClO4)2 (1), [Co(HL)3] [Co(NCS)4] (2) and NiL2, respectively. Both CoII complexes are high-spin, whereas the NiII complex is in lowspin state (diamagnetic). An x-ray analysis of (1) showed it to have a trans-trigonal bipyramidal configuration in which one coordination site in the equatorial plane is occupied by one H2O molecule. HL, a bidentate ligand, is coordinated via N(1) and N(4). The tris(ligand) cation in complex (2) has an octahedral configuration. Complex NiL2 has a square-planar configuration. The deep purple plate-like crystals of (1) are monoclinic with space group C2/c, having cell parameters:a=11.369(3), b=13.029(4), c=17.438(5) Å; β=103.39(2)o. The structure was solved by the heavy-atom method and refined by least-squares method to an R value of 0.060 for 1761 observed reflections. © 1989 Chapman and Hall Ltd. | en |
dc.relation.ispartof | Transition Metal Chemistry | en |
dc.title | Transition metal complexes with thiosemicarbazide-based ligands, Part IX. Cobalt(II) and nickel(II) complexes with 2-furaldehyde S-methylisothiosemicarbazone; crystal and molecular structure of aqua-bis(2-furaldehyde S-methylisothiosemicarbazone)cobalt(II)-diperchlorate | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.doi | 10.1007/BF01040609 | - |
dc.identifier.scopus | 2-s2.0-33644643787 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/33644643787 | - |
dc.description.version | Unknown | en_US |
dc.relation.lastpage | 142 | en |
dc.relation.firstpage | 139 | en |
dc.relation.issue | 2 | en |
dc.relation.volume | 14 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
Appears in Collections: | PMF Publikacije/Publications |
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