Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/14451
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Vojinović, Ljiljana | en_US |
dc.contributor.author | Leovac, Vukadin | en_US |
dc.contributor.author | Novaković, Slađana | en_US |
dc.contributor.author | Bogdanović, Goran | en_US |
dc.contributor.author | Čanadi, Janoš | en_US |
dc.contributor.author | Češljević, Valerija | en_US |
dc.date.accessioned | 2020-03-03T14:56:11Z | - |
dc.date.available | 2020-03-03T14:56:11Z | - |
dc.date.issued | 2004-01-01 | - |
dc.identifier.issn | 13877003 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/14451 | - |
dc.description.abstract | A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl 2 • 2H2O, and its octahedral cobalt(III) complexes [Co(HL)(NO2)3] • H2O (1) and [Co(HL) 2](PF6)3 (2) were synthesized and characterized by different physical measurements. The crystal structure of (1) has been determined by single crystal X-ray analysis. The crystal packing of the complex molecules is influenced by the presence of weak C-H...π and C-H...O interactions. A new ligand, pyridoxilidene Girard-T hydrazone, [H 3L]Cl2 • 2H2O, and its octahedral cobalt(III) complexes [Co(HL)(NO2)3] • H2O (1) and [Co(HL)2](PF6)3 (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, 1H and 13C NMR spectra. © 2004 Published by Elsevier B.V. | en |
dc.relation.ispartof | Inorganic Chemistry Communications | en |
dc.title | Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.doi | 10.1016/j.inoche.2004.09.016 | - |
dc.identifier.scopus | 2-s2.0-9244240265 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/9244240265 | - |
dc.description.version | Published | en_US |
dc.relation.lastpage | 1268 | en |
dc.relation.firstpage | 1264 | en |
dc.relation.issue | 12 | en |
dc.relation.volume | 7 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
crisitem.author.dept | Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.dept | Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.orcid | 0000-0002-8618-7819 | - |
crisitem.author.orcid | 0000-0003-3145-0752 | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
Appears in Collections: | PMF Publikacije/Publications |
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