Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/13331
DC Field | Value | Language |
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dc.contributor.author | Argay G. | en_US |
dc.contributor.author | Kálmán A. | en_US |
dc.contributor.author | Párkányi L. | en_US |
dc.contributor.author | Leovac, Vukadin | en_US |
dc.contributor.author | Brčeski, Ilija | en_US |
dc.contributor.author | Radivojsa P. | en_US |
dc.date.accessioned | 2020-03-03T14:51:54Z | - |
dc.date.available | 2020-03-03T14:51:54Z | - |
dc.date.issued | 2000-01-01 | - |
dc.identifier.issn | 00958972 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/13331 | - |
dc.description.abstract | The preparation and physical characterization of two copper(I) complexes Cu(HL)NO 3 and [Cu(HL) 2 ]NO 3 ⋯ MeOH formed with a newly synthesized tridentate [S,N,P] HL = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand and the crystal structure analysis of the latter have been carried out. An X-ray study of [Cu(HL) 2 ]NO 3 ⋯ MeOH revealed a copper(I) ion coordinated tetrahedrally to S,N,P,P atoms donated by two HL ligands. One is tridentate [S,N,P], whereas the second HL ligand is monodentate, ligating only its phosphorus atom to the copper. The geometry around the four-coordinate Cu(I) is comparable with Cu{N,S,P,X} tetrahedra (X = N, P, or S) retrieved from the Cambridge Structural Database. In addition, with a restriction to Cu{N,P,X,X} (X = C,N,P) tetrahedra - S is excluded - ca. 60 structures against three or four cases were found to be maintained by Cu(I) ions substantiating the principal role of the phosphorus ligands in the reduction of Cu(II) to Cu(I). | en |
dc.relation.ispartof | Journal of Coordination Chemistry | en |
dc.title | Transition metal complexes with thiosemicarbazide-based ligands. Part 37.* Synthesis and study of the first Thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(Diphenylphosphino)benzaldehyde Thiosemicarbazonato(-1)] copper(i)-nitrate-methanol solvate | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.scopus | 2-s2.0-0842289775 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/0842289775 | - |
dc.description.version | Unknown | en_US |
dc.relation.lastpage | 19 | en |
dc.relation.firstpage | 9 | en |
dc.relation.issue | 1 | en |
dc.relation.volume | 51 | en |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
Appears in Collections: | PMF Publikacije/Publications |
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