Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/12961
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Topalov A. | en |
dc.contributor.author | Molnár-Gábor D. | en |
dc.contributor.author | Abramović, Biljana | en |
dc.contributor.author | Korom S. | en |
dc.contributor.author | Peričin D. | en |
dc.date.accessioned | 2020-03-03T14:50:31Z | - |
dc.date.available | 2020-03-03T14:50:31Z | - |
dc.date.issued | 2003-08-21 | en |
dc.identifier.issn | 10106030 | en |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/12961 | - |
dc.description.abstract | The photocatalytic removal of the insecticide fenitrothion (IUPAC name: O,O-dimethyl O-4-nitro-m-tolyl phosphorothioate), C 9 H 12 NO 5 PS, from water suspension of TiO 2 , was investigated by following the disappearance of the original substance along with the formation and disappearance of intermediates via recording NMR ( 1 H and 31 P) and UV spectra, as well as by pH measurements. Based on the obtained data, a possible reaction mechanism was proposed. It was found that 31 P-NMR spectrometry can be successfully used to follow the kinetics of transforming organic into inorganic phosphorus in the course of the degradation (k a =9.2×10 -7 mol dm -3 min -1 , r=0.980 for the illumination period after 15 h). The rate of fenitrothion aromatic ring decomposition was followed by UV spectrometry during the illumination (k a =3.1×10 -6 mol dm -3 min -1 , r=0.989). The complete mineralization was attained after about 66 h of irradiation. © 2003 Elsevier B.V. All rights reserved. | en |
dc.relation.ispartof | Journal of Photochemistry and Photobiology A: Chemistry | en |
dc.title | Photocatalytic removal of the insecticide fenitrothion from water sensitized with TiO <inf>2</inf> | en |
dc.type | Journal/Magazine Article | en |
dc.identifier.doi | 10.1016/S1010-6030(03)00266-1 | en |
dc.identifier.scopus | 2-s2.0-0042804933 | en |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/0042804933 | en |
dc.relation.lastpage | 201 | en |
dc.relation.firstpage | 195 | en |
dc.relation.issue | 3 | en |
dc.relation.volume | 160 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
crisitem.author.dept | Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.orcid | 0000-0001-7009-8523 | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
Appears in Collections: | PMF Publikacije/Publications |
SCOPUSTM
Citations
33
checked on Nov 20, 2023
Page view(s)
19
Last Week
2
2
Last month
0
0
checked on May 10, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.