Please use this identifier to cite or link to this item: https://open.uns.ac.rs/handle/123456789/12840
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dc.contributor.authorAšanin D.en
dc.contributor.authorRajković S.en
dc.contributor.authorMolnar-Gabor D.en
dc.contributor.authorDjuran M.en
dc.date.accessioned2020-03-03T14:50:04Z-
dc.date.available2020-03-03T14:50:04Z-
dc.date.issued2004-01-01en
dc.identifier.issn00269247en
dc.identifier.urihttps://open.uns.ac.rs/handle/123456789/12840-
dc.description.abstractHydrolytic reactions between various palladium(II) complexes of the type cis-[Pd(L)(H 2 O) 2 ] 2+ in which L is ethylenediamine (en), 1,2-propylenediamine (1,2-pn), isobutylenediamine (ibn), 1,2-diaminocyclohexane (1,2-dach), N-methylethylenediamine (Meen), N,N,N′,N′,-tetramethylethylenediamine (Me 4 en), S-methyl L-cysteine (MeS-L-HCys), L-methionine (L-HMet), and 2,5-dithiahexane (dth) and dipeptide N-acetylated L-methionylglycine (MeCOMet-Gly) were studied by 1 H NMR spectroscopy. The reactions were carried out in the pH range 2.0-2.5 and at 50°C. In all these reactions, palladium(II) complex bound to a methionine residue effects the regioselective cleavage of the amide bond involving the carboxylic group of methionine. We found that the rate of hydrolysis and mechanism of this reaction are strongly dependent from the nature of the chelate ligand L in palladium(II) complexes of the type cis-[Pd(L)(H 2 O) 2 ] 2+ . © Springer-Verlag 2004.en
dc.relation.ispartofMonatshefte fur Chemieen
dc.titleHydrolysis of the peptide bond in N-acetylated L-methionylglycine catalyzed by various palladium(II) complexes: Dependence of the hydrolytic reactions on the nature of the chelate ligand in cis-[Pd(L)(H <inf>2</inf> O) <inf>2</inf> ] <sup>2+</sup> complexesen
dc.typeJournal/Magazine Articleen
dc.identifier.doi10.1007/s00706-004-0232-4en
dc.identifier.scopus2-s2.0-11244249502en
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/11244249502en
dc.relation.lastpage1453en
dc.relation.firstpage1445en
dc.relation.issue12en
dc.relation.volume135en
item.grantfulltextnone-
item.fulltextNo Fulltext-
crisitem.author.deptFilozofski fakultet, Odsek za filozofiju-
crisitem.author.orcid0000-0003-0901-4102-
crisitem.author.parentorgFilozofski fakultet-
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