Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/12176
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jovanović, Ljiljana | en_US |
dc.contributor.author | Bjelica, Luka | en_US |
dc.date.accessioned | 2020-03-03T14:47:30Z | - |
dc.date.available | 2020-03-03T14:47:30Z | - |
dc.date.issued | 1988-10-25 | - |
dc.identifier.issn | 00220728 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/12176 | - |
dc.description.abstract | The electrochemistry of some novel Fe(III) complexes of the type Fe(L)Cl involving several tetradentate ligands based on the bis-condensation products of S-methylisothiosemicarbazide with two either identical or different aldehydes (salicylaldehyde, its derivatives, or 2-hydroxy-1-naphthaldehyde), was studied in DMF solutions at a GC electrode. All complexes undergo a two-step one-electron reduction which is usually complicated by chemical reactions. In solutions containing Cl- (either from the complex, or added as LiCl), the Cl--DMF ligand exchange reaction takes place and is especially pronounced for the Fe(II) oxidation state. The stability of the chloride-containing complexes was discussed in detail in view of the coordinated ligand effect and the oxidation state of the central atom. Some relevant kinetic parameters are calculated. © 1988. | en |
dc.relation.ispartof | Journal of Electroanalytical Chemistry | en |
dc.title | Voltammetry of some novel Fe(III) complexes with tetradentate ONNO ligands. The axial ligand effect | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.doi | 10.1016/0022-0728(88)80221-3 | - |
dc.identifier.scopus | 2-s2.0-0345739433 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/0345739433 | - |
dc.description.version | Unknown | en_US |
dc.relation.lastpage | 360 | en |
dc.relation.firstpage | 345 | en |
dc.relation.issue | 2 | en |
dc.relation.volume | 252 | en |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
crisitem.author.dept | Prirodno-matematički fakultet, Departman za hemiju, biohemiju i zaštitu životne sredine | - |
crisitem.author.orcid | 0000-0001-8773-774X | - |
crisitem.author.parentorg | Prirodno-matematički fakultet | - |
Appears in Collections: | PMF Publikacije/Publications |
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