Please use this identifier to cite or link to this item:
https://open.uns.ac.rs/handle/123456789/11070
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Draškovic B. | en_US |
dc.contributor.author | Bogdanović G. | en_US |
dc.contributor.author | Leovac, Vukadin | en_US |
dc.contributor.author | Brčeski, Ilija | en_US |
dc.contributor.author | Poleti D. | en_US |
dc.date.accessioned | 2020-03-03T14:42:50Z | - |
dc.date.available | 2020-03-03T14:42:50Z | - |
dc.date.issued | 2006-01-01 | - |
dc.identifier.issn | 01082701 | en_US |
dc.identifier.uri | https://open.uns.ac.rs/handle/123456789/11070 | - |
dc.description.abstract | The title compound, [Ni(C 28 H 30 N 3 O 2 PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) A for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H⋯μ interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H⋯μ interactions dominate in the crystal packing. © 2006 International Union of Crystallography. | en |
dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | en |
dc.title | Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-Diphenylphosphino-α-ethoxybenzyl-κP)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-κO)thiosemicarbazido-κ2N1,N4]nickel(II) | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.doi | 10.1107/S0108270106018932 | - |
dc.identifier.scopus | 2-s2.0-33745949162 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/33745949162 | - |
dc.description.version | Unknown | en_US |
dc.relation.issue | 7 | en |
dc.relation.volume | 62 | en |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
Appears in Collections: | Naučne i umetničke publikacije |
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